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liquid crystal nanomaterial STM scanning tunneling microscopy AFM atomic force microscopy nanoparticle organize order disorder ordered nematic smectic magnetic field electric field organic semiconductor carbon nanotube optical microscopy surface science materials science university research chemistry physics physical chemistry mesogen phase transition publication simulation molecular nano nanometer nanoscience nanomaterial nanotechnology technology patent scanning probe microscopy rhk multimode spm atomic resolution nanometer scale oriented film monolayer David L Patrick David Patrick Dr. Patrick WWU Washington

Thin films research.

Thin films of organic compounds are important in many areas of science and technology, ranging from optics and electronics, to the control of adhesion, lubrication and corrosion. The way molecules are organized in thin films is therefore interesting both in its own right, as an issue for fundamental study, and because it influences a film's properties and function in practical applications.

Our research on thin films aims to understand how and why molecules organize themselves the way they do at two-dimensional interfaces, and also to develop new ways for controlling their organization.  In a research program at WWU spanning nearly a decade, we have studied many different aspects of molecular ordering at surfaces.  Currently our focus is on using liquid crystal solvents to control orientational order, polymorphism, chirality, and other structural properties.


References

Controlled symmetry breaking to grow chiral films from achiral molecules, A. Berg, D. L. Patrick, Angew. Chemie Int. Ed. 43, 1744 (2005).  preprint (PDF)

Controlling Molecular Alignment in an Organic Monolayer with a Sacrificial Liquid Crystal Template, S. Hickman, A. Hamilton, D. L. Patrick, Surface Science, 537, 113 (2003).   PDF

Chiral Symmetry Breaking in Interfacial Fluids of Achiral Molecules, P. Kohl, D. L. Patrick, J. Phys. Chem. B. 105, 8203 (2001).   PDF

Formation of Uniaxial Molecular Films by Liquid Crystal Imprinting in a Magnetic Field, J. D. Mougous, A. J. Brackley, K. Foland, R. T. Baker, D. L. Patrick Phys. Rev. Lett. 84, 2742 (2000).  Phys. Rev. Focus news story  PDF

Competitive Adsorption, Phase Segregation, and Molecular Motion at a Solid-Liquid Interface Studied by Scanning Tunneling Microscopy, R. T. Baker, J. D. Mougous, A. Brackley, and D. L. Patrick, Langmuir 15, 4884 (1999).  Journal cover  PDF

 


2-D chirality.
 


A domain boundary.

 

 


8CB on graphite

 

 


Tetracontane on graphite.
Each stick-like feature is one molecule.